John Harry MacMillan Ph.D.
PUBLICATIONS AND PATENTS
Below are listed in chronological order my
complete list of Chemistry Abstracts, Papers and Patents. Download freely any
material of interest.
1. Thomas R.P. Gibb Jr. and John H. MacMillan, "Line
Broadening in the X-Ray Diffraction Patterns of the Vanadium Hydride
System", Tufts University, Undergraduate Thesis, 1966.
FULL PAPER
(Google Document)
PDF
2. Thomas R.P. Gibb Jr., J.H. MacMillan and R.J. Roy, "The
Magnetic Susceptibility of Palladium Hydride", J. Phys. Chem., Vol. 70, p3024 (1966).
PDF
2a. Thomas R.P. Gibb Jr. and John H. MacMillan, "Magnetic
Susceptibility Effects on Removal of Hydrogen from Beta Phase Palladium Hydride",
Tufts University, Undergraduate Thesis, 1966.
FULL PAPER
(Google
Document) COMPLETE THESIS (Google Document)
3. Alfred Viola and John H. MacMillan, "Vapor Phase Thermolysis of
1-Hexen-5-yn-3-ol An Acetylenic Oxy-Cope Reaction" J. Amer. Chem. Soc., Vol. 90, p
6141, (1968).
PDF
4. Alfred Viola and John H. MacMillan, "A Novel Steric Effect in
the Thermolysis of Prop-2-ynyl Vinyl Carbinols" Chemical Communications p 301,
(1970). FULL
PAPER (Google Document)
PDF
5. Alfred Viola and John H. MacMillan, "The Vapor Phase Acetylenic
Oxy-Cope Reaction of 5-Hexen-1-yn-3-ol , The Chemistry of an Allenol Intermediate",
J. Amer. Chem. Soc., Vol. 92 p 2404, (1970).
PDF
6. Alfred Viola and John H. MacMillan,
"Addition of Grignard Reagents to Allylic and Propargylic Alcohols", J.H.
MacMillan, Ph.D. Thesis, Northeastern University, 1970.
FULL
PAPER (Google Document)
PDF
6a. John H. MacMillan and Alfred Viola,
"Addition of unsaturated propargyl, allyl and benzyl Grignard Reagents to acetylenic
or allylic alcohols.", internet archive, 2012.
PDF FULL
PAPER (Google Document)
7. Alfred Viola and John H. MacMillan, " Investigation of Possible Phenyl Participation
in the Oxy-Cope and Acetylenic Oxy-Cope Rearrangements" J.H. MacMillan, Ph.D.
Thesis, Northeastern University, 1970.
PDF
FULL
PAPER (Google Document)
8. "Triple
Bond Participation in the Oxy-Cope Rearrangement", John H. MacMillan, Ph.D.
Thesis, Northeastern University, 1970.
9. Alfred Viola and John H. MacMillan,
"Vapor Phase Thermolysis of 1,5-Hexadiynes, Effect of Hydroxyl Substitution".
Presented at the 159th National Meeting of the American Chemical Society Houston Texas,
February 1970, Abstract # ORGN 50.
FULL PAPER (Google Document)
PDF
9a. John H. MacMillan and Alfred Viola "
The
Acetylenic-Oxy-Cope Rearrangement of 1,5-Hexadiyne-3-ol and Methyl Substituted
Derivatives", Internet Archive, 2012.
10. Alfred Viola, John H.
MacMillan, Robert J. Proverb and Brian L. Yates, "Participation of Acetylenic Bonds
in Pericyclic Reactions, Thermal Cleavage of Beta-Hydroxyacetylenes", J. Amer. Chem.
Soc., Vol. 93 p 6967, (1971).
PDF
11. Alfred Viola, John H. MacMillan, Robert J. Proverb and Brian L.
Yates, "Reaction Rates by Flow System Thermolysis, The Competitive Components of the
Oxy-Cope Reaction", Chemical Communications, p 936, (1971).
PDF
12. John H. MacMillan and Stephen S. Washburne,
"Further Studies of the Interaction of Carbonyl Compounds with Organometallic
Azides, the Novel Reaction of Benzoquinone with Trimethylsilyl Azide", Report of
Investigators to the National Cancer Institute, 1972.
FULL PAPER (Google Document)
PDF
13. "Further Studies of the
Interaction of Carbonyl Compounds with Organometallic
Azides, the Reaction of Napthoquinones with
Trimethylsilyl Azide",
Report of Investigators to the National Cancer
Institute, 1972.
FULL
PAPER (Google Document)
PDF
14. John H. MacMillan and Stephen S. Washburne "Further
Studies of the Interaction of Carbonyl Compounds with Organometallic Azides, the
Reaction of Acrylonitrile with Trimethylsilyl Azide".
Report of Investigators to the National Cancer Institute,
1973.
15. John H. MacMillan and Stephen S. Washburne, "Interaction of
Carbonyl Compounds with Organometallic Azides Part V., Sorboyl Chloride and its Conversion
to an Alpha-Pyridone", J. Org. Chem., Vol. 38, p 2982, (1973).
PDF
16. John H. MacMillan and Stephen S. Washburne, "Lanthanide
Chemical Shift Reagents as Tools for Determining Isomer Distributions in
2,4-Hexadieneoates and Related Compounds", Organic Magnetic Resonance, Vol. 6., p250,
(1974).
PDF
16a. Supplemental Unpublished Notebook Chemical Shift
Data Supporting Paper 16 above.
FULL
PAPER (Google Document)
17. John H. MacMillan, "Recent Examples of Selectivity in
Catalysis" Strem Chemiker, Vol. 11 No. 2, July 1974.
FULL
PAPER (Google Document)
FULL
PAPER (Google Document, in Japanese)
18. John H. MacMillan, Michael E. Strem,
Fredrick A. Fowler and George Guy, "An Improved Method for the
Preparation of Bis-DiphenylPhosphino Acetylene and unsymmetrical Aryl Substituted
Diphenylphosphino Acetylenes", Strem Chemiker, Vol. 11, No. 2, July 1974.
FULL
PAPER(Google Document)
PDF
19. James D. Warren, John H. MacMillan and Stephen S.
Washburne, "Synthesis of Substituted 2H-1,3-Oxazine-2,6-Diones by Reaction of
Trimethylsilyl Azide with Maleic Anhydrides", J.Org.Chem., Vol. 40, p 743, (1975).
PDF
20. John H. MacMillan and Stephen S. Washburne,
"Further Investigation of the Interaction of Trimethylsilyl Azide with Substituted
Maleic Anhydrides, Synthesis of 4-and 5-Aryl Substituted 1,3(3H) Oxazine-2,6-Diones",
J.Heterocyclic Chemistry, Vol. 12, p 1215, (1975).
PDF
20a. Supplemental Additional 4 and 5-Aryl
Substituted 1,3(3H) Oxazine-2,6-Diones.
Google
Document
PDF
21. Mark Lenhart, John H. MacMillan, Alice
Maragliano and Steven S. Washburne, "A Facile General Synthesis of Aryl Maleic
Anhydrides", Temple University, 1976. Presented at the 10th Middle Atlantic Regional
Meeting of the American Chemical Society Philadelphia Pa. February, 1976, Paper # 10,
Undergraduate research.
FULL
PAPER(Google Document)
PDF
22. John H. MacMillan and Stephen S.
Washburne, "Hydrolysis reactions of the 4-and
5-Alkyl or Aryl Substituted 1,3(3H) Oxazine-2,6-Diones (Oxauracil) Ring System",
Temple University, 1977, Report to the U.S. Army Medical Research and Development command;
Grant Number DAMD 17-74-C4100.
FULL
PAPER (Google
Document)
PDF
23. John H. MacMillan, "Improved Procedure for the
Preparation of "Oxauracil", 2H-1,3(3H)-Oxazine-2,6-Dione", Organic
Preparations and Procedures Int. Vol 9., p 87, (1977).
PDF
24. John H. MacMillan and Mortimer M. Labes, "Low
Transition Temperature Liquid Crystalline Amines Incorporating the Trans-1,4-Cyclohexane
Ring System", Molecular Crystals and Liquid Crystals, Vol. 55, p 61, (1979).
25. John H. MacMillan and Mortimer M. Labes,
"Induced Phases in Terminal Mixtures of Polar Liquid Crystalline Amines and
Nitriles", Mol. Crystals and Liquid Crystals Letters, Vol. 56, p7, (1979).
PDF
26. John H. MacMillan and Mortimer M. Labes, "Low
Transition Temperature Liquid Crystalline Amines Incorporating the Biphenyl Ring
System", Mol. Crystals and Liquid Crystals Letters, Vol. 56, p51, (1979).
PDF
27. John H. MacMillan and Mortimer M. Labes,
"Synthesis and Photochemistry of Chiral Liquid Crystalline Nitrones", Poster
Session Gordon Research Conference, Liquid Crystals Santa Barbara, California, January,
1980.
POSTER(Google
Document) FULL
PAPER(Google Document)
PDF
28. Eugene R. Bertozzi and John H. MacMillan,
"Hexamethylene Glycol Polyformal Copolymers for Insulating Glass and Building
Sealants", Thiokol Corporation, Company Private, Sept 15, 1980.
PDF
29. John H. MacMillan and Mortimer M. Labes, "Amine
Substituted Liquid Crystal Compositions", U.S. Patent #4,293,193, Oct. 6, 1981.
PDF
30. John H. MacMillan, Eugene R. Bertozzi and Bruce E.
Streeter, "One Package Heat Curable Sealant Compositions", U.S. Patent
#4,430,489, Feb. 7, 1984.
PDF
31. John H. MacMillan, Eugene R. Bertozzi and Bruce E.
Streeter, "Thioether Modified Polymer Compositions", U.S. Patent #4,590,240, May
20, 1986.
European Patent
(Google Document)
PDF
32. "Is a Totally Constructivist Approach to
the Teaching of High School Chemistry Possible in Practice?", John H. MacMillan
Ph.D.
Beaver College, (Arcadia University), 1992.
Google
Document
PDF
33.
"Virtual Chemistry Laboratory for Non-Science Majors, Good or Bad?", John H.
MacMillan Ph.D.
Beaver College, (Arcadia University), 1995.
Google
Document
PDF
34. John H. MacMillan, "Using Silanes
as Adhesion Promoters", United Chemical Technologies Technical Workshop, 1997,
Presented at 214th Meeting of the American Chemical Society, Los Vegas, Nevada 1997, and
the 215th Meeting of the American Chemical Society, Dallas ,Texas , 1998.
Google Document
PDF
35. John H. MacMillan,"Formulating Silicone
Adhesives, Rubbers and Gels", United Chemical Technologies Technical Workshop, 1998.
Google
Document
PDF
Presented at the 220th National Meeting
of the American Chemical Society, Washington, D.C. 2000.
36. John H. MacMillan, "Silane Surface Modifying
Reagents", United Chemical Technologies Technical Publication, 1998.
37."A method for derivatizing surfaces with aldehyde
groups by employing a new alkoxy aldehydic silane", Coyne, Ann N., Benner, Lauren.,
MacMillan, John H., Telepchak, Michael T, United Chemical Technologies,
technical publication, 2001.
Google
Document Google
Document (link 2)
PDF
38. John H. MacMillan, "Homogeneous
Platinum Catalysts", United Chemical Technologies Technical Workshop, Presented at
the 222nd Natioinal Meeting of the American Chemical Society, Chicago, Illinois, 2001.
Google
Document
PDF
39. Marzinke; Marla (Ft. Washington, PA); MacMillan;
John H. (Ambler, PA); August; Thomas F. (Glenolden, PA); Telepchak; Michael J. (Yardley,
PA); "Method for the preparation of aminopropyl or aminoalkyl functional polyalkyl or
aryl siloxanes".
United States Patent 6,177,583, January 23, 2001.
Google
Document Link
PDF
40. Wayne King, John H. MacMillan and Michael J.
Telepchak, "Siloxane modified carboxylic acid substituted amines and salts
thereof", U.S. Patent 6,489,499, December 3, 2002.
Link
Google
Document
PDF
41. Ann N. Coyne, John H. MacMillan and Michael J.
Telepchak, "Supported aldehydic silanes and method of manufacture",
U.S. Patent 6,589,799, July 8, 2003.
Link
Google
Document
PDF
42. Ann N. Coyne, John H. MacMillan and Michael J.
Telepchak, "Supported aldehydic silanes and method of manufacture", U.S. Patent
7,045,365, May 16, 2006.
Link
Google
Document
PDF
43. John H. MacMillan "
Oxidative dehydration of aryl substituted succinic acids with selenium dioxide;
4-Bromophenyl maleic anhydride".
45. John H. MacMillan "Oxazine-2,6-dione N-methylation
with dimethyl sulfate; N-Methyl-4-(4-methylphenyl)-1,3(3H)-oxazine-2,6-dione".
46. John H. MacMillan and Alfred Viola, " Preparation
of acetylenic alcohols by addition of propargyl Grignard reagents activated at low
temperatures with mercury ion to a,ß-unsaturated aldehydes and ketones", Internet
Archive, 2012.
47. John H. MacMillan "Addition of propargyl Grignard
to aldehyde; 1-Phenyl-3-butyne-1-ol".
Chemspider February 17, 2012
PDF
Papers Presented at Professional Meetings